Cyclopalladated complexes containing 2-C6R4PPh2 ligands (R = H, F): one-electron electrochemical reduction leading to metal–carbon σ-bond cleavage via palladium(i)
نویسندگان
چکیده
منابع مشابه
Pathways for C-H bond cleavage of propane σ-complexes on PdO(101).
We used dispersion-corrected density functional theory (DFT-D3) calculations to investigate the initial C-H bond cleavage of propane σ-complexes adsorbed on the PdO(101) surface. The calculations predict that propane molecules adsorbed in η(1) configurations can undergo facile C-H bond cleavage on PdO(101), where the energy barrier for C-H bond activation is lower than that for desorption for e...
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Diiron complexes containing pyridyl-phosphine ligands, that is, (mu-pdt)[Fe(2)(CO)(5)L] (pdt = S(CH(2))(3)S, L = Ph(2)PCH(2)Py, Ph(2)PPy, ) and (micro-pdt)[Fe(CO)(2)(PMe(3))][Fe(CO)(2)L] (L = Ph(2)PCH(2)Py, Ph(2)PPy, ) were prepared as model complexes of the [FeFe]-hydrogenase active site. Protonation of and by HOTf afforded the pyridyl-nitrogen protonated products [H(N)][OTf] and [H(N)][OTf], ...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2015
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c4dt03268c